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Ultrafast X-Rays Reveal Elusive Critical Point in Supercooled Water

The result offers a concrete path to explain water’s odd behavior at everyday conditions.

Overview

  • Researchers reported in Science on Thursday, March 26, that water has a second critical point near 210 K and about 1,000 atmospheres.
  • Scientists melted amorphous ice with an infrared pulse and used X-ray shots at the Pohang facility to probe the liquid in the “no man’s land” before it froze.
  • The measurements show two supercooled liquid states, a high-density and a low-density form, become one at that point in line with long-standing theory.
  • The finding helps tie water’s density peak at 4 °C and its unusual heat capacity and compressibility to fluctuations that spread out from this critical region.
  • Experts note the ultrafast snapshots assume the liquid reached equilibrium, so new tests will check that assumption and explore impacts across chemistry, geology, biology, and climate.