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HKUST COF Electrolyte Pushes Calcium-Ion Battery to 1,000-Cycle Lab Performance

Redox-active frameworks delivered faster Ca2+ transport with high room-temperature conductivity in Advanced Science research.

Overview

  • The quasi-solid-state electrolyte reached ionic conductivity of 0.46 mS cm−1 and a Ca2+ transport number greater than 0.53 at room temperature.
  • A full calcium-ion cell delivered 155.9 mAh g−1 at 0.15 A g−1 and retained over 74.6% capacity after 1,000 cycles at 1 A g−1.
  • Experimental measurements and simulations show rapid Ca2+ movement along aligned carbonyl groups inside ordered COF pores.
  • The study was led by Prof. Yoonseob Kim at HKUST with collaborators at Shanghai Jiao Tong University, with results reported by Zhuoyu Yin et al.
  • The team presents the technique as a potential lithium-ion alternative, though the findings remain at laboratory scale and require further development.